ACS Technology
Providing
Pathogen Control and
Extend Shelf-Life
with
"ACS"
Acidic Calcium Sulfate
" USDA & FDA Approved "
'width' is a duplicate attribute name. Line 1, position 37. Litchi (Lychee) Fruit
Salmonella & Listeria m Control Treatment
"pHixr 100" Pathogen Control-Processing Water Treatment'width' is a duplicate attribute name. Line 1, position 37.
USDA Research Project: INTEGRATED APPROACH TO QUALITY MAINTENANCE AND EVALUATION OF INTACT AND FRESH-CUT PRODUCE
Location: Food Quality Laboratory
Title: Maintaining quality of litchi fruit
with "Acidified Calcium Sulfate"
 |
Wang, Chien |
|
Chen, Hangjun - |
|
Jin, Peng - |
|
Gao, Haiyan - |
|
Submitted to: Journal of Agricultural and Food Chemistry
Publication Type: Peer Reviewed Journal Publication Acceptance Date: June 22, 2010 Publication Date: August 11, 2010 Citation: Wang, C.Y., Chen, H., Jin, P., Gao, H. 2010. Maintaining quality of litchi fruit with acidified calcium sulfate. Journal of Agricultural and Food Chemistry. 58:8658-8666. Interpretive Summary: Two of the most serious problems affecting the postharvest quality of litchi fruit are decay and browning or loss of red color on the peel of the fruit. We found that treatment of litchi fruit with acidified calcium sulfate, a GRAS (Generally Recognized As Safe) compound, could inhibit the mold growth, prevent browning and retain red color of the peel. We also showed that this treatment did not have any adverse effect on the internal quality of the litchi fruit including soluble solids, sugar, and organic acid content. Information obtained in this study is of interest to other scientists and will be useful and beneficial to the litchi fruit industry and consumers. Technical Abstract: The effect of acidified calcium sulfate (ACS) on quality of litchi (Litchi chinensis Sonn. cv `Brewster") fruit after harvest was evaluated. ACS at 1.25% or higher concentrations significantly inhibited the activities of polyphenoloxidase and peroxidase in pericarp during storage at both 5 and 10 ºC. These treatments also effectively prevented browning and retained red color of the outer shell of the fruit. Total phenolic and total anthocyanin content in pericarp were increased by the ACS treatments at the dose dependent manner. The radical scavenging activities for ROO", DPPH*, "OH and O2"- were also enhanced by ACS, particularly by 2.5 and 5% concentrations. The activities of several antioxidant enzymes and enzymes of ascorbate-glutathione cycle including catalase, ascorbate peroxidase, glutathione peroxidase, glutathione reductase, dehydroascorbate reductase, and monodehydroascorbate reductase gradually declined during storage. However, ACS enhanced the activities of these enzymes especially at the beginning of the storage. Samples treated with ACS generally had higher flavonoid levels then the control. The two major flavonoids, cyanidin-3-rutinoside and cyaniding-3-glucoside, were found to be significantly increased by 2.5 and 5.0% ACS at both 5 and 10 ºC. No differences were detected among various treatments in soluble solids content, sugar, and organic acid levels in the pulp of litchi fruit, indicating that the internal quality of the fruit was not affected by the ACS treatment. |
Food microbiology has shown that good food hygiene and food safe temperatures along with use of ACS Technology Inc. SafepHix brand Acidic Calcium Sulfate, ACS 100, will control Salmonella Listeria, diseases in food and other hazards in food. This has proven beneficial for controlling Salmonella and Campylobacter with use of ACS Technology SafepHix brand Acidic Calcium Sulfate, Freshphix or pHesh-phix 100, for antimicrobial effectiveness vegetable wash and vegetable cleaner on whole vegetables.
Food industry leaders implement a food protection program using ACS Technology SafepHix brand ACS 100, acidic calcium sulfate, to insure quality control of food and any disease of bacteria. Safety in the food industry is paramount for food quality management and quality control of meat and poultry. Preventing bacterial food contamination, bacteria food poisoning or foodborne illnesses, such a campylobacter, Listeria m or salmonella food illness is essential food safety in food industry.
Fruit & Vegetables Salmonella Treatment
pHixr I00 pH Reducer & Process Water Acidulant
MATERIAL SAFETY DATA SHEET
Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION
PRODUCT NAME Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant EMERGENCY NUMBER 800-424-9300
|
3 |
HEALTH |
HAZARD RATING 4=EXTREME 3=HIGH 2=MODERATE 1=SLIGHT 0=INSIGNIFICANT |
|
0 |
FIRE |
|
|
2 |
REACTIVITY |
|
|
C |
MINIMUM PERSONAL PROTECTION |
|
|
A=GOGGLES B=GOGGLES & GLOVES C=GOGGLES, GLOVES, & APRON |
||
MSDS NUMBER 14076-H PRODUCT USE Acidulant
VERSION NUMBER 1.0 DOT HAZARD CLASS 8
ISSUE DATE: 09/04/07 DOT SHIPPING NAME: Corrosive liquid, Acidic,
Inorganic, N.O.S.
REVISION DATE: 09/09/07 UN NUMBER 3264
PREPARED BY: ACS Technology PACKAGING GROUP II
MANUFACTURER Hydrite Chemical Co for
ACS Technology
719-265-9141
ABBREVIATION KEY: NA= Not Applicable NE = Not Established ND = Not Determined
Section 2 – HAZARDOUS INGREDIENTS INFORMATION
CHEMICAL INDENTITY HAZARDOUS CAS REG# PERCENTAGES
Acidic Calcium Sulfate Yes NA 40 – 60
Water No 7732-18-5 40 – 60
Section 3 – PHYSICAL DATA
BOILING POINT: – 104ºC – 105ºC SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 28 - 1.30 ODOR: – Odorless and slightly acidic
FREEZING POINT: - 5ºC
Section 4 – HEALTH HAZARD DATA
Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal. Harmful if undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant is inhaled. Excessive heat (>100OC) may cause volatility. Slightly water reactive. Contains strong inorganic acid.
POTENTIAL HEALTH EFFECTS
Inhalation: Inhalation of undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant may produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat. May cause lung edema, a medical emergency.
Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant.
Ingestion: Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant is a food additive, however ingestion of undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner may cause burns to the mouth, throat, and stomach.
Eye Contact: Contact with undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant may cause blurred vision, redness, pain & severe tissue burns.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant.
Section 5 – FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
ACS TECHNOLOGY Page 3 of 3 MSDS I4076-H – Fruit & Vegetables Salmonella Treatment
Section 6 – FIRE FIGHTING MEASURES
Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10).
Explosion: A mild exothermic reaction may occur when undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant is added to water.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.
Section 7 – ACCIDENTAL RELEASE MEASURES
Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer.
Section 8 – HANDLING AND STORAGE
Store in well ventilated storage area. Protect from physical damage. Keep away from incompatible materials. When diluting, always add Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant to water; never add water to undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant.
Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION
Airborne Exposure Limits:
For undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant.
-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)
-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL), A2 - suspected human carcinogen for undiluted pHixr I00 contained in strong inorganic acid mists.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench
facilities in work area.
Section 10 – STABILITY AND REACTIVITY
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
Hazardous Polymerization: Will not occur.
Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.
Conditions to Avoid: Excessive Heat (>100OC) and incompatibles.
Section 11 – TOXICOLOGICAL INFORMATION
Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).
Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).
Section 12 – ECOLOGICAL INFORMATION
Environmental Fate: When released into the soil, this undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.
Environmental Toxicity: This undiluted Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant may be toxic to aquatic life.
ACS TECHNOLOGY Page 3 of 3 MSDS I4076-H – Fruit & Vegetables Salmonella Treatment
Section 13 – DISPOSAL CONSIDERATIONS
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 – TRANSPORTATION
Shipping Name: Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE) Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant
Hazard Class: 8
UN Number: UN3264
Packing Group: II
Section 15 – REGULATORY INFORMATION
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals in Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in pHixr Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant are under a Chemical Test Rule.
Section 12b
None of the chemicals in Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material, Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant , have a SNUR under TSCA.
SARA
Section 313
Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in pHixr Fruit & Vegetables Salmonella Treatment - pHixr I00 pH Reducer & Process Water Acidulant are considered highly hazardous by OSHA.
STATE
CAS# 7664-93-9 can be found on the following state right to know lists:
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Section 16 – ADDITIONAL INFORMATION
MSDS Creation Date: 6/20/2005
Revision #3 Date: 6/20/2006
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages
ACS TECHNOLOGY Page 3 of 3 MSDS I4076-H – Fruit & Vegetables Salmonella Treatment
MATERIAL SAFETY DATA SHEET
Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION
PRODUCT NAME pHixr I00 EMERGENCY NUMBER 800-424-9300
|
3 |
HEALTH |
HAZARD RATING 4=EXTREME 3=HIGH 2=MODERATE 1=SLIGHT 0=INSIGNIFICANT |
|
0 |
FIRE |
|
|
2 |
REACTIVITY |
|
|
C |
MINIMUM PERSONAL PROTECTION |
|
|
A=GOGGLES B=GOGGLES & GLOVES C=GOGGLES, GLOVES, & APRON |
||
MSDS NUMBER 14076-H PRODUCT USE Acidulant
VERSION NUMBER 1.0 DOT HAZARD CLASS 8
ISSUE DATE: 09/04/07 DOT SHIPPING NAME: Corrosive liquid, Acidic,
Inorganic, N.O.S.
REVISION DATE: 09/09/07 UN NUMBER 3264
PREPARED BY: ACS Technology PACKAGING GROUP II
MANUFACTURER Hydrite Chemical Co for
ACS Technology
719-265-9141
ABBREVIATION KEY: NA= Not Applicable NE = Not Established ND = Not Determined
Section 2 – HAZARDOUS INGREDIENTS INFORMATION
CHEMICAL INDENTITY HAZARDOUS CAS REG# PERCENTAGES
Acidic Calcium Sulfate Yes NA 40 – 60
Water No 7732-18-5 40 – 60
Section 3 – PHYSICAL DATA
BOILING POINT: – 104ºC – 105ºC SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 28 - 1.30 ODOR: – Odorless and slightly acidic
FREEZING POINT: - 5ºC
Section 4 – HEALTH HAZARD DATA
Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal. Harmful if undiluted pHixr I00 is inhaled. Excessive heat (>100OC) may cause volatility. Slightly water reactive. pHixr 100 Contains strong inorganic acid.
POTENTIAL HEALTH EFFECTS
Inhalation: Inhalation of undiluted pHixr I00 may produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat. May cause lung edema, a medical emergency.
Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted pHixr I00.
Ingestion: pHixr I00 is a food additive, however ingestion of undiluted pHixr I00 may cause burns to the mouth, throat, and stomach.
Eye Contact: Contact with undiluted pHixr I00 may cause blurred vision, redness, pain & severe tissue burns.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted pHixr I00.
Section 5 – FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Section 6 – FIRE FIGHTING MEASURES
Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10).
Explosion: A mild exothermic reaction may occur when undiluted pHixr I00 is added to water.
ACS TECHNOLOGY Page I of 3 MSDS I4076-H – pHixr I00
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.
Section 7 – ACCIDENTAL RELEASE MEASURES
Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer.
Section 8 – HANDLING AND STORAGE
Store in well ventilated storage area. Protect from physical damage. Keep away from incompatible materials. When diluting, always add pHixr I00 to water; never add water to undiluted pHixr I00.
Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION
Airborne Exposure Limits:
For undiluted pHixr I00.
-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)
-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL), A2 - suspected human carcinogen for undiluted pHixr I00 contained in strong inorganic acid mists.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench
facilities in work area.
Section 10 – STABILITY AND REACTIVITY
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
Hazardous Polymerization: Will not occur.
Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.
Conditions to Avoid: Excessive Heat (>100OC) and incompatibles.
Section 11 – TOXICOLOGICAL INFORMATION
Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).
Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).
Section 12 – ECOLOGICAL INFORMATION
Environmental Fate: When released into the soil, this undiluted pHixr I00 may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.
Environmental Toxicity: This undiluted pHixr I00 may be toxic to aquatic life.
Section 13 – DISPOSAL CONSIDERATIONS
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 – TRANSPORTATION
Shipping Name: Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE)
Hazard Class: 8
UN Number: UN3264
Packing Group: II
ACS TECHNOLOGY Page 2 of 3 MSDS I4076-H – pHixr I00
Section 15 – REGULATORY INFORMATION
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 313
pHixr I00 may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7664-93-9 can be found on the following state right to know lists:
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Section 16 – ADDITIONAL INFORMATION
MSDS Creation Date: 6/20/2005
Revision #3 Date: 6/20/2006
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages
ACS TECHNOLOGY Page 3 of 3 MSDS I4076-H – pHixr I00
pHixr 100 pH Reducer / Acidifier / Water Conditioner
MATERIAL SAFETY DATA SHEET
Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION
PRODUCT NAME pHixr I00 pH Reducer / Acidifier / Water conditioner EMERGENCY NUMBER 800-424-9300
|
3 |
HEALTH |
HAZARD RATING 4=EXTREME 3=HIGH 2=MODERATE 1=SLIGHT 0=INSIGNIFICANT |
|
0 |
FIRE |
|
|
2 |
REACTIVITY |
|
|
C |
MINIMUM PERSONAL PROTECTION |
|
|
A=GOGGLES B=GOGGLES & GLOVES C=GOGGLES, GLOVES, & APRON |
||
MSDS NUMBER 14076-H PRODUCT USE Acidulant
VERSION NUMBER 1.0 DOT HAZARD CLASS 8
ISSUE DATE: 09/04/07 DOT SHIPPING NAME: Corrosive liquid, Acidic,
Inorganic, N.O.S.
REVISION DATE: 09/09/07 UN NUMBER 3264
PREPARED BY: ACS Technology PACKAGING GROUP II
MANUFACTURER Hydrite Chemical Co for
ACS Technology
719-265-9141
ABBREVIATION KEY: NA= Not Applicable NE = Not Established ND = Not Determined
Section 2 – HAZARDOUS INGREDIENTS INFORMATION
CHEMICAL INDENTITY HAZARDOUS CAS REG# PERCENTAGES
Acidic Calcium Sulfate Yes NA 40 – 60
Water No 7732-18-5 40 – 60
Section 3 – PHYSICAL DATA
BOILING POINT: – 104ºC – 105ºC SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 28 - 1.30 ODOR: – Odorless and slightly acidic
FREEZING POINT: - 5ºC
Section 4 – HEALTH HAZARD DATA
Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal. Harmful if undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner is inhaled. Excessive heat (>100OC) may cause volatility. Slightly water reactive. Contains strong inorganic acid.
POTENTIAL HEALTH EFFECTS
Inhalation: Inhalation of undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner may produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat. May cause lung edema, a medical emergency.
Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner.
Ingestion: pHixr I00 pH Reducer / Acidifier / Water conditioner is a food additive, however ingestion of undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner may cause burns to the mouth, throat, and stomach.
Eye Contact: Contact with undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner may cause blurred vision, redness, pain & severe tissue burns.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner.
Section 5 – FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Section 6 – FIRE FIGHTING MEASURES
Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10).
Explosion: A mild exothermic reaction may occur when undiluted pHixr I00 is added to water.
ACS TECHNOLOGY Page I of 3 MSDS I4076-H – pHixr I00 pH Reducer / Acidifier / Water Conditioner
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.
Section 7 – ACCIDENTAL RELEASE MEASURES
Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer.
Section 8 – HANDLING AND STORAGE
Store in well ventilated storage area. Protect from physical damage. Keep away from incompatible materials. When diluting, always add pHixr I00 pH Reducer / Acidifier / Water conditioner to water; never add water to undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner.
Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION
Airborne Exposure Limits:
For undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner.
-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)
-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL), A2 - suspected human carcinogen for undiluted pHixr I00 contained in strong inorganic acid mists.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench
facilities in work area.
Section 10 – STABILITY AND REACTIVITY
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
Hazardous Polymerization: Will not occur.
Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.
Conditions to Avoid: Excessive Heat (>100OC) and incompatibles.
Section 11 – TOXICOLOGICAL INFORMATION
Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).
Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).
Section 12 – ECOLOGICAL INFORMATION
Environmental Fate: When released into the soil, this undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.
Environmental Toxicity: This undiluted pHixr I00 pH Reducer / Acidifier / Water conditioner may be toxic to aquatic life.
Section 13 – DISPOSAL CONSIDERATIONS
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 – TRANSPORTATION
Shipping Name: Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE) pHixr I00 pH Reducer / Acidifier / Water conditioner
Hazard Class: 8
UN Number: UN3264
Packing Group: II
ACS TECHNOLOGY Page 2 of 3 MSDS I4076-H – pHixr I00 pH Reducer / Acidifier / Water Conditioner
Section 15 – REGULATORY INFORMATION
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals in pHixr I00 pH Reducer / Acidifier / Water conditioner are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in pHixr I00 pH Reducer / Acidifier / Water conditioner are under a Chemical Test Rule.
Section 12b
None of the chemicals in pHixr I00 pH Reducer / Acidifier / Water conditioner are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material, pHixr I00 pH Reducer / Acidifier / Water conditioner, have a SNUR under TSCA.
SARA
Section 313
pHixr I00 pH Reducer / Acidifier / Water conditioner may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in pHixr I00 pH Reducer / Acidifier / Water conditioner are considered highly hazardous by OSHA.
STATE
CAS# 7664-93-9 can be found on the following state right to know lists:
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Section 16 – ADDITIONAL INFORMATION
MSDS Creation Date: 6/20/2005
Revision #3 Date: 6/20/2006
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages
ACS TECHNOLOGY Page 3 of 3 MSDS I4076-H – pHixr I00 pH Reducer / Acidifier / Water Conditioner
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